Silver perchlorate is a white solid, very soluble in water. Perchlorate is a polyatomic ion, which means it is a charged molecule. Perchloric acid is an aqueous solution containing hydrogen ions and perchlorate ions. It can also be reduced to elemental silver with many common metals, like iron, zinc. The calcium acetylide commonly called calcium carbide is a major compound of commerce. Silver perchlorate is an ionic compound with the formula AgClO4. Similar to silver nitrate, silver perchlorate is an effective reagent for replacing halides ligands with perchlorate, which is a weakly or non-coordinating anion. This reaction is represented by the general scheme: Silver(I) oxide is the chemical compound with the formula Ag2O. Let's learn about silver perchlorate's formula, and solubility. The term also is applied incorrectly to the different process of forming nitrate esters between alcohols and nitric acid. It is a useful source of the Ag+ ion, although the presence of perchlorate presents risks. imaginable degree, area of Let's look at two of these reactions. Historically, pyridine was produced from coal tar. They are floating freely in the solution. Preparation. In organic chemistry, the Baudisch reaction is a process for the synthesis of nitrosophenols using metal ions. Solubility Silver perchlorate is noteworthy for its solubility in aromatic solvents such as benzene (52.8 g/L) and toluene (1010 g/L). KClO4 has the lowest solubility of the alkali metal perchlorates (1.5 g in 100 mL of water at 25 °C). Silver perchlorate is noteworthy for its solubility in aromatic solvents such as benzene (52.8 g/L) and toluene (1010 g/L). Log in here for access. Availability. It is a highly flammable, weakly alkaline, water-miscible liquid with a distinctive, unpleasant fish-like smell. Usually found as an aqueous solution, this colorless compound is a stronger acid than sulfuric acid and nitric acid. Pyridine is colorless, but older or impure samples can appear yellow. Acetylides are reagents in organic synthesis. Create your account, Already registered? Alternatively, it can be prepared by the reaction between barium perchlorate and silver sulfate, or from the reaction of perchloric acid with silver oxide. This salt is a versatile precursor to many other silver compounds, such as those used in photography. 2HClO4 (aq) + Ag2 O (s) → 2AgClO4 (aq) + H2 O (l). It is used as a catalyst in organic chemistry. The water would evaporate, leaving behind the solid silver perchlorate. It was once called lunar caustic because silver was called luna by the ancient alchemists, who associated silver with the moon. Enter your email address below and we will send you your username, If the address matches an existing account you will receive an email with instructions to retrieve your username, I have read and accept the Wiley Online Library Terms and Conditions of Use. Precipitation is defined as the creation of a solid from a solution. Silver perchlorate can be neutralized by reducing it with metallic iron. All that has to be done to isolate the silver perchlorate is to heat the solution to evaporate the water. Contents The precipitate-free liquid remaining above the solid is called the 'supernate' or 'supernatant'. The silver ion and the perchlorate ion will stick together to form a neutral ionic compound with the formula AgClO4. They are floating freely in the solution. InChI=1S/Ag.ClHO4/c;2-1(3,4)5/h;(H,2,3,4,5)/q+1;/p-1, InChI=1/Ag.ClHO4/c;2-1(3,4)5/h;(H,2,3,4,5)/q+1;/p-1, Except where otherwise noted, data are given for materials in their, "Low-Temperature Neutron Diffraction Study of the Silver Perchlorate–Benzene π Complex". Silver perchlorate is the chemical compound with the formula AgClO 4.This white solid forms a monohydrate and is mildly deliquescent.It is a useful source of the Ag + ion, although the presence of perchlorate presents risks. Its name derives from the molecule tropine from which cycloheptatriene (tropylidene) was first synthesized in 1881. You can test out of the Form Supplied in: white crystalline anhydride; white crystalline monohydrate [14242‐05‐8]. Silver perchlorate is a chemical compound with the formula AgClO4.